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Rate constants for the bimolecular self-reaction of tertbutyl radicals in nalkane solvents (1976)

Schuh, H. ; Fischer, H.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 8 (1976), S. 341-356

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Rate constants for the self-reaction of tertbutyl radicals in six nalkanes are determined as functions of temperature by kinetic electron-spin resonance spectroscopy and from rates of product formation. They are well described by a Smoluchowski-Stokes-Einstein treatment including effects of microfriction and spin statistical factors, indicating complete diffusion control. The ratio of disproportionation to combination products is found to depend on temperature and solvent. This is tentatively ascribed to reorientational effects in the encounter pairs.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550080303

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