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Very-low-pressure pyrolysis (VLPP) of group IV (A) tetramethyls: Neopentane and tetramethyltin (1979)

Baldwin, Alan C. ; Lewis, Karan E. ; Golden, David M.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 11 (1979), S. 529-542

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The decomposition of neopentane was studied using the very-low-pressure pyrolysis (VLPP) technique at temperatures from 1000 to 1260 K. The derived Arrhenius parameters \documentclass{article}\pagestyle{empty}\begin{document}$$ {log k(sec}^{{ - 1}} {) = 17}{.3 - 80}{.8/}\theta { at 1000 K } $$\end{document} are consistent with δHf0(t-butyl) = 8.4 kcal/mol. Using the above A factor, data on the decomposition of tetramethyltin yield DH0(Sn(CH3)3 - CH3) = 69 ± 2 kcal/mol.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550110506

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