ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rate constants determined for the thermal dimerization of chlorotrifluoroethene to dichlorohexafluorocyclobutane at 404-672 K have been correlated with previously published results. For the temperature range of 404-800 K, \documentclass{article}\pagestyle{empty}\begin{document}$$ k{ = 1}{.08} \times { 10}^{{ - 9}} { T }^{{4}{.02}} { exp ( - 86,700/RT) m}^{3} {/mol} \cdot \sec $$\end{document} The dependence of the preexponential factor on temperature corresponds to a value of 17 J/K·mol for the difference in heat capacity (ΔCp±) between the activation complex and the reactant.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550110605
