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The rate constant for H + i-C4H8 → t-C4H9 in the range of 298-563 K (1981)

Canosa, Carlos E. ; Marshall, Roger M. ; Sheppard, Adrian

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 295-301

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The overall rate constant for hydrogen-atom addition to isobutene has been measured in the temperature range of 298-563 K in a flow discharge system coupled to a quadrupole mass spectrometer. Previously published results allow the determination of \documentclass{article}\pagestyle{empty}\begin{document}$$ \log {\rm }k_1 ({\rm cm}^3 /{\rm mol\,\, sec}) = 13.59 \pm 0.11 - 1.79 \pm 0.19\,\,{\rm kcal/mol/(2}{\rm .3}RT{\rm)} $$\end{document} where the error limits are 95% confidence limits.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550130308

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