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Electron transfer from α-aminoalkyl radicals to methyl viologen (1984)

Kim-Thuan, Nguyen ; Scaiano, J. C.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 371-377

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reactions of tert-butoxyl radicals with amines, leading to the formation of α-aminoalkyl radicals, and the reactions of these with the electron acceptor methyl viologen have been examined using laser flash photolysis techniques. For example, the radicals CH3ĊHNEt2 and HOCH2ĊH N(CH2CH2OH)2 react with methyl viologen with rate constants equal to (1.3 ± 0.1) × 109 and (2.1 ± 0.4) × 109M-1 · s-1, respectively, in wet acetonitrile at 300 K.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550160407

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