ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the gas phase reactions of NO2 with a series of organics have been studied at 295 ± 2 K. It was observed that only 2,3-dimethyl-2-butene and the conjugated dialkenes studied reacted at observable rates, with rate constants which ranged from 1.5 × 10-20 cm3 molecule-1 s-1 for 2,3-dimethyl-2-butene to 1.3 × 10-17 cm3 molecule-1 s-1 for α-phellandrene. These rate constants are compared with the available literature data and the mechanisms of these reactions are discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550160607