Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
16 (1984), S. 781-792
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The thermal decomposition of azoisopropane (AIP) was studied in the presence of various quantities of propylene in the temperature and pressure intervals 498-553 K and 3.33-5.33 kPa. The inhibition functions relating to formation of the products were determined; these proved a good basis for interpretation of the formation of the secondary decompositon products of AIP. The experimental data support the conception that the βμ radical - radical reactionoccurs. The product of this is not stable; its decomposition is one of the sources of the secondary products. The ratio of the rate constants was determined for the following reactions:
Additional Material:
12 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550160613
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