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Gas phase reactions of CF3, C2F5, and n-C3F7 with carbon tetrachloride (1984)

de Vöhringer, C. M. ; Staricco, E. H.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 1351-1356

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 × 1013 cm3 mol-1 s-1 for the self-combination rate constant of all radicals are: TextReactionlog(A/cm3 mol-1 s-1)E/kcal mol-1CF3 + CCl412.811.3C2F5 + CCl412.811.6n-C3F7 + CCl412.912.0

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550161107

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