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Kinetics and mechanism of the pyrolysis of 1-Chloro-1, 1-difluoroethane in the presence of chlorine (1986)

Huybrechts, G. ; Hubin, Y.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 18 (1986), S. 497-504

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The first stage thermal reactions of CF2CICH3 in the presence of chlorine have been studied between 554 and 614 K. These are and \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CF}_{\rm 2} {\rm CICH}_{\rm 3} {\rm + CI}_{\rm 2} \to {\rm CF}_{\rm 2} {\rm CICH}_{\rm 2} {\rm CI + HCI} $$\end{document} Rate equations derived from a radical mechanism are shown to fit the experimental results. Values of Arrhenius parameters for the decomposition of the CF2ClCH2. radical and its reactions with Cl2 and Cl are given.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550180408

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