ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rate constants for overall H-atom abstraction by hydroxyl radicals from C—H and O—H bonds are estimated for alkanes, haloalkanes, aldehydes, ketones, ethers, alcohols, nitriles, and nitrates over thetemperature range 250-1000 K. These estimated rate constants utilize the modified Arrhenius expression K = A'T2e-E'/T in combination with the recommendations given in the recent review and evaluation of OH radical kinetics of Atkinson [1]. This estimation procedure gives good agreement, generally to within better than a factor of 2, of the estimated rate constants with theserecommendations.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180506
