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Theory of fast multiple bond-switching reactions: NO + NH2 (1986)

Gilbert, Robert G. ; Whyte, Andrew R. ; Phillips, Leon F.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 18 (1986), S. 721-737

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A theoretical treatment is given for fast, multiple bond-switching reactions, such as NO + NH2 → N2 + H2O. These reactions are characterized by all or most of the bonds being broken. The collision complex involved (whether long or short lived) is shown to be extremely anharmonic. Consideration of the master equation describing the competing processes of complex formation, internal rearrangement and collisional deactivation yields easily applied sufficient conditions for the recombination rate coefficient being independent of pressure.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550180702

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