ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rate constants have been determined at (298 ± 4) K for the reactions: and the relaxation processes: Time-resolved HF(1,0) emission was observed following the photolysis of F2 with pulses from an excimer laser operating on XeCl (λ = 308 nm). Analysis of the emission traces gave first-order constants for reaction and relaxation, and their dependence on [H2O] and [HCN] yielded: \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{1{\rm a}} = (1.3 \pm 0.1) \times 10^{ - 11} {\rm cm}^{\rm 3} {\rm molecule}^{{\rm - 1}} s^{ - 1} $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{1{\rm b}} = (1.3 \pm 0.1) \times 10^{ - 10} {\rm cm}^{\rm 3} {\rm molecule}^{{\rm - 1}} s^{ - 1} $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{2{\rm a}} = (3.7 \pm 0.4) \times 10^{ - 13} {\rm cm}^{\rm 3} {\rm molecule}^{{\rm - 1}} s^{ - 1} $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{2{\rm b}} = (3.4 \pm 0.2) \times 10^{ - 12} {\rm cm}^{\rm 3} {\rm molecule}^{{\rm - 1}} s^{ - 1} $$\end{document}
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180808
