ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The microcanonical variational transition states of the isotopic reactions H + T2 and T + H2 are shown to migrate with increasing energy in opposite directions away from the classical barrier, i.e., into the reactant and product valleys, respectively. The energy dependence of this isotopic shift is examined and excitation functions are reported, both for collinear and near-collinear reactions.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180914