ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
For the rate constant of addition of tert-butyl radicals to acrylonitrile at T = 300 K in solution modulated ESR spectroscopy and muon spin rotation yield 106 M-1 s-1 and 2.4 × 106 M-1 s-1. The addition of pivaloyl radical to acrylonitrile proceeds with Arrhenius parameters log A/M-1 s-1 = 7.7 and Ea = 11.5 kJ/ mol. The results are discussed in terms of polar effects in radical addition reactions.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550181002