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Rate constants for one-electron oxidation by methylperoxyl radicals in aqueous solutions (1986)

HUIE, Robert E. ; NETA, P.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 18 (1986), S. 1185-1191

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Rate constants for one-electron oxidation by the methylperoxyl radicals (CH3O2, HOCH2O2, -O2CCH2O2, and CCI3O2) in aqueous solutions have been measured by pulse radiolysis and found to be in the range of 3 × 105 to 6 × 108 M-1 s-1 for compounds with redox potentials between 0.6 and 0.1 V. Substitution on the methylperoxyl radical with OH or CO2- has only a minor effect on the rate of oxidation but substitution with three chlorines increases the rate constants by two orders of magnitude. The redox potential of the CH3O2 radical is estimated to be 0.6-0.7 V.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550181007

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