ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The near U-V photolysis of t-butyl nitrite has been studied over the temperature range 303-393 K. Under these conditions t-butyl nitrite was shown to be a very clean photochemical source of t-butoxy radicals. This allows a study of the decomposition of the t-butoxy radical to be made over this temperature range (3). Extrapolation of the rate constants k3 to high pressure and combination with our previous thermal data give the results: \documentclass{article}\pagestyle{empty}\begin{document}$$k_3 (\infty)/{\rm s}^{{\rm - 1}} = 10^{14.04 \pm 0.37} \exp (- 7519 \pm 70.5/T)$$\end{document}
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550210705
