ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the reactions CH3O + Cl → H2CO + HCl (1) and CH3O + ClO → H2CO + HOCl (2) have been studied using the discharge-flow techniques. CH3O was monitored by laser-induced fluorescence, whereas mass spectrometry was used for the detection or titration of other species. The rate constants obtained at 298 K are: k1 = (1.9 ± 0.4) × 10-11 cm3 molecule-1 s-1 and k2 = (2.3 ± 0.3) × 10-11 cm3 molecule-1 s-1. These data are useful to interpret the results of the studies of the reactions of CH3O2 with Cl and ClO which, at least partly, produce CH3O radicals. © 1996 John Wiley & Sons, Inc.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.4
