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On the apparent compensation effect found for two parallel reactions (1998)

Budrugeac, P. ; Segal, E.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 30 (1998), S. 673-681

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The authors present a critical analysis of the use of an overall single reaction rate equation instead of the true rate equations corresponding to the decomposition of a substance according to two parallel reactions. Isothermal as well as nonisothermal decomposition are considered. An apparent compensation effect has been evidenced in both cases. It has been assigned to the dependence of the kinetic parameters on temperature (for the isothermal case), conversion, and heating rate (for nonisothermal one). © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 673-681, 1998

Additional Material: 11 Ill.

Type of Medium: Electronic Resource

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