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Sur l'aminolyse des amides. II. Action catalytique des acides (1954)

Jaunin, R. ; Beretta Piccoli, M. ; Charalambous, T.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 37 (1954), S. 216-221

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Details

ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: As an example of aminolysis of amides, the reaction between acetanilide and o-anisidine has been studied with special reference to the catalytic action of acids. In the case of a weak acid, the rate of aminolysis increases continuously as the concentration of the catalyzing acid is increased; on the other hand, in the case of a strong acid, the rate passes through a maximum value. A mechanism for aminolysis of amides, consistent with these facts, is suggested.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19540370126

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