ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The exclusive product of thermal rearrangement of (±)-7-isopropylidene-2,3-diazabicyclo[2.2.1]hept-2-ene N-oxide (2) has been identified as the title compound (1). The compound crystallizes in the orthorhombic space group Pbca (No. 61), with a= 8.953 (2), b= 12.740 (2), c=14.446 (3) Å; Z= 8; px=1.227 g cm-3. The details of the molecular structure are not unusual, except for a long C-N distance (C(8)-N(7), 1.560 (4) Å). No significant short intermolecular contacts are observed in the crystal.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19800630522