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Digitale Medien

Hyperbolic Reaction Curves with Concentration-Independent Relaxation Times (1984)

Balakrishnan, Karappulli P. ; Gampp, Harald ; Zuberbühler, Andreas D.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 67 (1984), S. 2155-2160

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Details

ISSN: 0018-019X

Schlagwort(e): Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Hyperbolic reaction curves with concentration-independent relaxation times are obtained from the simple reaction scheme A⇌I + P; A + I → P. While a mathematically perfect hyperbola is only obtained, if two of the three rate constants are accidentally degenerate, the same function can still be used as a very close approximation in the general case, and the differences may go unnoticed even for well-defined stopped-flow experiments. In view of the simplicity of the reaction, it is suggested that reaction curves with second-order (hyperbolic) shapes, but concentration-independent relaxation times may be a common feature in chemical kinetics.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/hlca.19840670815

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