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Crystal Structures of Chiral Ionophores: Bis(9,9′-spirobifluorene)-26-crown-4 and -32-crown-6 (1986)

Egli, Martin ; Dobler, Max

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 69 (1986), S. 626-631

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The X-ray crystal structures of bis(9,9′-spirobifluorene)-26-crown-4βbenzene solvate (monoclinic, a = 15.47 Å, b 11.265 Å, c = 15.220 Å, β = 91.54°, space group C2) and bis(9,9′-spirobifluorene)-32-crown-6·dichloromethane solvate (tetragonal, a = 20.958 Å, c = 11.779 Å, space group P41212) are described. Both compounds act as enantioselective ionophores for α-aminoalcohols.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19860690312

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