ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Charge transfer in adsorbate-substrate systems has been studied in the limiting case of an unperturbed substrate extending the Anderson-Newns treatment to two- and three-dimensional substrates. This allows comparison of different chemisorption sites within an essentially analytic treatment. Important changes of the local densities of states with respect to the usual one-dimensional model are obtained. The resulting charge transfers are of the same order of magnitude as those obtained by adding correlation effects to the one-dimensional Anderson-Newns model.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560260516
