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Invalidity of the ubiquitous mass-velocity operator in quasirelativistic theories (1986)

Farazdel, Abbas ; Smith, Vedene H.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 29 (1986), S. 311-314

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The general problem of relativistic corrections to the kinetic energy in quasirelativistic theories, is discussed and related formulas are developed. It is shown that the well-known mass-velocity operator, Hmv = (-α2/8)p4, is incorrect and does not provide any proper relativistic corrections.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560290304

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