ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The experimental technique of electron momentum spectroscopy (EMS) (i.e., binary (e, 2e) spectroscopy) is discussed together with typical examples of its applications over the past decade in the area of experimental quantum chemistry. Results interpreted within the framework of the plane wave impulse and the target Hartree - Fock approximations provide direct measurements of, spherically averaged, orbital electron momentum distributions. Results for a variety of atoms and small molecules are compared with calculations using a range of Fourier transformed SCF position space wavefunctions of varying sophistication. Measured momentum distributions (MD) provide a “direct” view of orbitals. In addition to offering a sensitive experimental diagnostic for semiempirical molecular wavefunctions, the MD's provide a chemically significant, additional experimental constraint to the usual variational optimization of wavefunctions. The measured MD's clearly reflect well known characteristics of various chemical and physical properties. It appears that EMS and momentum space chemistry offer the promise of supplementary perspectives and new vistas in quantum chemistry, as suggested by Coulson more than 40 years ago. Binding energy spectra in the inner valence region reveal, in many cases, a major breakdown of the simple MO model for ionization in accord with the predictions of many-body calculations.Results are considered for atomic targets, including H and the noble gases. The measured momentum distribution for H2 is also compared with results from Compton scattering. Results for H2 and H are combined to provide a direct experimental assessment of the bond density in H2, which is compared with calculations. The behavior of the outer valence MD''s for small row two and row three hydride molecules such as H2O and H2S, NH3, HF, and HCl are consistent with well known differences in chemical and physical behavior such as ligand-donor activity and hydrogen bonding. MD measurements for the outermost valence orbitals of HF, H2O and NH3 show significant differences from those calculated using even very high-quality wavefunctions. Measurements of MD's for outer σg orbitals of small polyatomic molecules such as CO2, COS, CS2, and CF4 show clear evidence of mixed s and p character. It is apparent that EMS is a sensitive probe of details of electronic structure and electron motion in atoms and molecules.
Additional Material:
15 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560290534
