ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Crystal and Molecular Structure of Dimeric DimethylaminodimethylindiumDimeric dimethylamino-dimethylindium was prepared by splitting off methane from the adduct Me3In—NHMe2 and characterized by its vibrational spectra. The structure - determined by X-ray analysis - has shown to have the monoclinic space group P21/c with a = 7.601, b = 7.336, c = 14.927 Å and β = 119.9°. Patterson, Fourier and Difference synthesis were used for determing the structure, which was refined by least square analysis to an R value of 0.068.
Notes:
Dimeres Dimethylamino-dimethylindium wurde durch Methanabspaltung aus dem Addukt Me3In—Me2NH dargestellt und schwingungsspektroskopisch charakterisiert. Die Röntgenstrukturanalyse führte zu der monoklinen Raumgruppe P21/c mit a = 7,601, b = 7,336, c = 14,927 Å und β = 119,9°. Die Struktur wurde aus Patterson-, Fourier- und Differenz-Fourier-Synthesen abgeleitet und nach der Methode der kleinsten Fehlerquadrate bis zu einem R-Wert von 0,068 verfeinert.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19774290114
