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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 435 (1977), S. 156-160 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Mass Spectrometric Investigations on the Systems MCl2/AlCl3 (M = Cr, Co, Pd)The reactions MCl2,s + Al2Cl6,g = MAl2Cl8,g (M = Cr, Co, Pd) have been investigated by a double-oven evaporation cell in connection with mass spectrometric analysis. All Ions, containing both, M and Al, have under our conditions one neutral percusor, the molecule MAl2Cl8,g. The evaluated equilibrium constants agree with literature data.
    Notes: Mit Hilfe einer Doppelzellenanordnung in Verbindung mit einem Massenspektrometer wurden die Reaktionen MCl2,f + Al2Cl6,g = MAl2Cl8,g (M = Cr, Co, Pd) untersucht. Die Analyse der Massenspektren ergab, daß bei unseren Versuchsbedingungen praktisch alle gleichzeitig M- und Al-haltigen Ionen auf die neutralen Gasmolekeln MAl2Cl8,g zurückzuführen sind. Die ermittelten Gleichgewichtskonstanten stimmen befriedigend mit Literaturangaben überein.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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