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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 454 (1979), S. 175-180 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structure of Triaquo-(2-methyl-2,4-dicarboxy-thiazolidinato)cobalt(II)A new compound which was obtained as crystals in small amounts by attemps to get cysteinato complexes of cobalt proved to be the complex triaquo-(2-methyl-2,4-dicarboxythiazolidinato)cobalt(II) based on a X-ray structure analysis (1501 reflections, R = 0.039). The dianion of the thiazolidine dicarbonic acid acts in it as a terdentate ligand. The remaining three coordination positions of the cobalt ion are occupied by water molecules. The complex compound crystallizes orthorhombic, space group P212121 with a = 595.5, b = 1264.7, c = 1439.0 pm and Z = 4.
    Notes: Eine neue Verbindung, die bei Versuchen zur Darstellung von Cystein-Komplexen des Cobalts als Nebenprodukt in Form von Kristallen angefallen war, erwies sich auf Grund der Röntgenstrukturanalyse (1501 Reflexe, R = 0,039) als ein Triaquo-(2-methyl-2,4-dicarboxy-thiazolidinato)cobalt(II). Das Dianion der Thiazolidin-dicarbonsäure fungiert darin als ein dreizähniger Ligand. Die drei restlichen Koordinationsstellen des Cobalt-Ions werden von Wassermolekülen besetzt. Die Komplexverbindung kristallisiert orthorhombisch, Raumgruppe P212121, mit a = 595,5, b = 1264,7, c = 1439,0 pm und Z = 4.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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