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  • 1
    ISSN: 0044-2313
    Keywords: Intermetallic phases (ternary) ; lithium ; 4A metals ; 5B elements ; preparation ; crystal structure ; X-ray ; neutron scattering ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Ternary Intermetallic Phases of Lithium, Transition Metals of the 4th Group and Elements of the 5th Maingroup with Statistical Metal Distribution in the „Cation“-SubstructureThe results of X-ray investigations and neutron diffraction on new and in some cases already known [1, 2] ternary intermetallic phases of Lithium with transition metals of the 4th group (b) and those of the 5th main group (X = P, As, Sb, Bi) will be reported. They crystallize in a partly „filled“ antifluorite type structure with a statistical Li/B-distribution in the tetrahedral sites. The structures are obviously stabilized by small amounts of enclosed d-elements.
    Notes: Es wird über Röntgenstrukturuntersuchungen und Neutronenbeugung an neuen und einigen schon bekannten [1, 2] ternären intermetallischen Phasen des Lithiums mit Elementen der 4. Nebengruppe (B) und Elementen der 5. Hauptgruppe (X = P, As, Sb, Bi) berichtet. Sie kristallisieren in einer teilweise „aufgefüllten“ Antifluorit-Struktur mit statistischer Li/B-Besetzung der Tetraederlücken, die offenbar durch den Einbau von geringen Mengen der Übergangsmetalle stabilisiert wird.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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