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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 947-950 
    ISSN: 0044-2313
    Keywords: Dimethyl zinc ; thermal decomposition ; oligomer organozinc compounds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Thermal Decomposition of Dimethyl ZincThe thermal decomposition of dimethyl zinc has been investigated in a static system between 588 and 673 K in the pressure range from 8 to 372 mbar. Gaseous products are methane, ethylene, ethane, propane, propylene and butane. The formation of a new solid product of the composition CH3(ZnCH2)xZnCH3 (x = 3,2…4,0) has been detected.
    Notes: Die thermische Zersetzung von Dimethylzink wird unter statischen Bedingungen im Temperaturintervall von 588 bis 673 K und im Bereich der Anfangsdrücke des Edukts von 8 bis 372 mbar untersucht. Gasförmige Produkte sind Methan, Ethylen, Ethan, Propylen und Butan. Es wird die Bildung eines neuartigen Feststoffes der Zusammensetzung CH3(ZnCH2)xZnCH3 (x = 3,2-4,0) nachgewiesen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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