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  • 1
    Electronic Resource
    Electronic Resource
    Magnetic coupling between two phenoxyl radicals attached to the phenyl rings of CIS- and trans-stilbenes (1994)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 7 (1994), S. 43-49 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Magnetic coupling between two sterically protected phenoxyl radicals through the cis- and trans-stilbene chromophores was studied by means of their EPR fine structures. While the zero-field splitting parameters D, which are governed by the magnitude of dipolar coupling, were dependent on the geometrical isomerism, the sign of exchange coupling was independent of it and dictated by the topology of the π-conjugated systems: ferromagnetic in o,m-isomers and antiferromagnetic in m,m'-isomers.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610070108
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