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The volume profile for a cheletropic reaction (1994)

Isaacs, Neil S. ; Laila, Abdulhameed

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 7 (1994), S. 178-180

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The volumes of activation and of reaction were measured for the reaction between sulphur dioxide and 2,3-dimethylbuta-1,3-diene to form 3,4-dimethylsulpholene. Values of ΔV and ΔV* are -33 and -35 cm3 mol-1, respectively in accordance with a concerted reaction having a very product-like transition state.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610070403

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