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Relative thermodynamic stabilities of the isomeric propenylbenzenes (1994)

Taskinen, Esko ; Lindholm, Nina

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 7 (1994), S. 256-258

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The relative thermodynamic stabilities of 2-propenylbenzene (allylbenzene), and the E and Z forms of 1-propenylbenzene were determined over the temperature range 50-170°C by chemical equilibration in DMSO solution with t-BuOK as catalyst. The values of the thermodynamic parameters ΔG⊖, ΔH⊖ and ΔS⊖ at 298·15 K for each isomerization reaction between the title compounds were evaluated.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610070507

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