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  • 1
    Electronic Resource
    Electronic Resource
    Aqueous solvation effect on the prototropic tautomerism of 2-thiocytosine (1995)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 8 (1995), S. 395-399 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Free energies of solvation were calculated for the four most stable gas-phase tautomeric forms of 2-thiocytosine (TC) using a local field SCF procedure with the solvation model SM2. The calculated changes in the free energies for each pair of tautomers reveal that all six possible equilibria tend to produce the thione-amino TC(1, 8, 8) and TC(3, 8, 8) species. This is in agreement with UV and ionization constant data.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610080603
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