ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of the copper (II) chelates of norephedrine (I), N-methylnorephedrine (II), N-ethylnorephedrine (III), and N-n-butylnorephedrine (IV) with benzoyl peroxide, cumene hydroperoxide, and 2,2′-diphenyl-1-picrylhydrazyl have been studied. Only the chelates of N-alkyl-substituted norephedrines enter into the reactions with free radicals, while their reactivity increases with the length of the alkyl substituent in the amino group of the ligand. The decomposition of cumene hydroperoxide was catalyzed by all four chelates; the catalytic efficiency increases in the order I〈II〈III 〈 IV.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1974.170120303
