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ESR studies of trapped free radicals and polymer deposition in xylene plasmas (1978)

Scott, Thomas W. ; Chu, Keh-Chang ; Venugopalan, M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 3213-3218

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Rates of polymer deposition and radical trapping in xylene plasmas produced in a Siemens tube with 60-Hz current decreased linearly with increasing flow rate but increased linearly with power and decreased in the order ortho 〉 meta 〉 para at a constant flow rate and pressure. These results indicate that radical recombination and disproportionation are unimportant and that the polymerization rate equation is first order in free radical concentration.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1978.170161215

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