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Singlet oxygen reactions with model compounds of cis- and trans-polyisoprene containing one unit. Kinetic aspects (1979)

Tanielian, C. ; Chaineaux, J.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 715-729

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: We have studied the rose bengal-sensitized photooxygenation of cis- and trans-polyisoprene model compounds that contain one unit in methanolic solution, characterized the resulting monohydroperoxides, and determined their yield. We have also demonstrated the possibility of a second addition of singlet oxygen on the same unit and have undertaken a kinetic study to determine the rate constants of all the reactions of 4-methyl-4-octene.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1979.170170310

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