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2,4-Dimethyl-3-pentanone-sensitized photopolymerization of vinyl monomers (1979)

Encina, M. V. ; Lissi, E. A.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 1645-1653

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The initiation quantum yield in the bulk photopolymerization of vinyl monomers sensitized by 2,4-dimethyl-3-pentanone has been measured for several monomers. The results obtained were interpreted in terms of a mechanism that considers singlet and triplet photocleavage of the ketone, competing with the quenching by the monomer. The quenching process does not lead to free radicals that can initiate the polymerization.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1979.170170608

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