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Digitale Medien

Properties of poly(p-phenylene)s and the perdeuterated analog (1982)

Hsing, Chih-Fen ; Khoury, Issam ; Bezoari, Massimo D. ; [weitere]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 3313-3323

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Details

ISSN: 0360-6376

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: ESR data for poly(p-phenylene) (PPP) prepared from benzene and catalyst-oxidant systems were compared with data for PPP obtained by a variety of other methods. The results were similar, except for the Yamamoto preparation, and comparable to the spin densities for heterocyclic polymers of thiophene, pyrrole, and selenophene. Deuterated PPP from C6D6 showed significant differences in properties, in comparison to ordinary PPP, in relation to molecular weight, color, solubility, and spins/g in electron spin resonance (ESR). The implications are discussed with regard to the mechanism of benzene polymerization by AlCl3-CuCl2.

Zusätzliches Material: 4 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1982.170201206

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