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Digitale Medien

Redox-initiated cationic polymerization: The diaryliodonium salt/benzoin redox couple (1983)

Crivello, J. V. ; Lee, J. L.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 1097-1110

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Details

ISSN: 0360-6376

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: A new redox couple based on the copper-catalyzed reduction of diaryliodonium salts with benzoins has been used to initiate cationic polymerizations of cyclic ethers and esters. A proposed mechanism for initiation by this redox couple is based on its stoichiometry and on the nature of the products. It was concluded that initiation of polymerization occurs both by direct arylation of the monomer and by protonation by strong Brønsted acids. The polymerization of several typical cationically polymerizable monomers using this new redox initiator were studied.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1983.170210417

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