Electronic Resource
New York
:
Wiley-Blackwell
Journal of Polymer Science Part A: General Papers
3 (1965), S. 3275-3278
ISSN:
0449-2951
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Isopropenylcarborane could not be polymerized by conventional radical and ionic methods. A low molecular weight polymer of DP = 10 was obtained by the use of aluminum chloride as catalyst at 150-170°C. Carboranylmethyl acrylate was homopolymerized and copolymerized with fluoroacrylates by using benzoyl peroxide as catalyst. The Tg of the homopolymer was about 165°C. The difficulty in polymerizing the isopropenylcarborane and the high Tg value for carboranylmethyl acrylate polymer have been partially attributed to the steric requirements of the carborane group.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1965.100030921
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