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Block copolymer formation from copolymers of phenylvinylene carbonate (1972)

Mulvaney, J. E. ; Sasaki, Y.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 3503-3508

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ISSN: 0449-296X

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Copolymers of phenylvinylene carbonate with styrene and p-chlorostyrene are readily prepared with radical initiators. The carbonate portion of the copolymers has been hydrolyzed to a 1,2-glycol which was then oxididatively cleaved with periodate-perman-ganate to produce a polymer with carboxyl and keto endgroups. Block copolymers were then prepared by conversion of the carboxyl groups to an acid chloride, followed by coupling with diols or a diamine.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1972.170101206

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