ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The viscoelastic properties of some polyester-urethanes are compared with the properties of other polymers. The behavior observed is anomalous in that these polyurethanes exhibit an unusually high value of modulus well above their Tg, unaccounted for by either crosslinking or crystallinity. Various experiments including incorporation of plasticizes of widely varying chemical composition have suggested interpretation of the system as a block copolymer, each block having its own Tg. Each of the two types of blocks seems to associate with similar blocks from other molecules.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1966.070101204