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Digitale Medien

Intramolecular reactions in vinyl polymers as a means of investigation of the propagation step (1946)

Merz, E. ; Alfrey, T. ; Goldfinger, G.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 1 (1946), S. 75-82

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Details

ISSN: 0022-3832

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The Flory-Wall expressions for the fraction of substituents remaining on a vinyl copolymer, when substituents are removed at random from adjacent 1,3 positions, are extended to the case of nonrandom copolymerization. A copolymer composition equation is derived for the case in which the type of monomer preceding the active freeradical chain end affects the propagation reaction. The distribution of lengths of sequences in copolymers is discussed.

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1946.120010202

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