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Kinetics of polymerization of vinyl benzoate (1959)

Banerjee, S. ; Muthana, M. S.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 37 (1959), S. 469-483

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Vinyl benzoate was polymerized in bulk as well as in solution, using benzoyl peroxide and azobisisobutyronitrile initiator at a temperature of 79.6°C. The overall rate of polymerization was found to be proportional to the concentration of the monomer and to the square root of the initiator concentration. Polymerization progressed to a normal extent, except that it increased with conversion, probably because of transfer with polymer. The value of the transfer constants with the monomer, initiator, and some solvents are reported.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1959.1203713217

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