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A fourier-transform infrared spectroscopic study of the hydrolytic stability of silane coupling agents on E-glass fibers (1980)

Ishida, Hatsuo ; Koenig, Jack L.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 1931-1943

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Details

ISSN: 0098-1273

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Fourier-transform (FT) infrared spectroscopy has been applied to the study the hydrothermal degradation of various coupling agents on E-glass fibers. The coupling agents studied include γ-methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane, and cyclohexyltrimethoxysilane. The amount of coupling agents on E-fibers was measured as a function of immersion time in water at 80°C. Structural changes were also followed by obtaining FT-IR difference spectra of the coupling agent on the glass fiber surface. Silanes desorb quite differently depending on the organofunctional groups. The resistance to desorption is strongly influenced by the organization of the silane interphase as well as the solubility of the silane in water.

Zusätzliches Material: 11 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1980.180180906

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