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Digitale Medien

Inclusion of mobile crosslinks and lateral crystallite growth in the theory of stress-induced crystallizationCorrected proofs received October 18, 1982 (1983)

Smith, K. J.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 45-53

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Details

ISSN: 0098-1273

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The theory of stress-induced crystallization is broadened to include a reshuffling of crosslink positions as a result of changing sizes of crystalline domains and multiple crystallites of varying lateral dimensions (i.e., lateral growth). A continuous state of equilibrium throughout the amorphous component of the stretched network is postulated and, consequently, effected by requiring crosslinks to anchor about their most probable locations, which vary continuously as crystallization changes. Such features incorporated into Flory's model of stress-induced crystallization broaden its theoretical base, placing it on a stronger, more realistic foundation.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1983.180210104

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