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Digitale Medien

Interdependence of motional processes in polymers: correlation functions for nmr relaxationCorrected proofs received November 22, 1982 (1983)

Henrichs, P. M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 263-274

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Details

ISSN: 0098-1273

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The roles of both anisotropic motion and the interdependence of multiple motions in leading to nonexponential correlation functions for NMR relaxation data are explored. A motional model is developed in which rotational motions of segments of various lengths are controlled by the formation and disappearance of a suitable conformation. Such a model gives correlation functions which can be made, through adjustment of parameters, to be almost identical to correlation functions from other, quite different, models. The ability of NMR relaxation data to identify unique motional models is thus questioned.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1983.180210208

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