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Poly 4-(3-chloropropyl)styrene: Syntheses of monomer, polymerization, characterizations, and thermal degradation of polymer (1989)

Montheard, J. P. ; Boinon, B. ; Benayad, B.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 2539-2551

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Details

ISSN: 0887-624X

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: 4-(3-Chloropropyl)styrene, a new functionalized styrene, has been synthesized in three steps from 3-chloropropylbenzene or in two steps from 4-chlorostyrene, and the polymerization has been carried out in bulk, with azobisisobutyronitrile as an initiator. The polymer has been characterized by its molecular weights, glass transition temperature, and NMR spectra. Thermal degradation has also been studied and volatile fractions characterized by GC-MS. A mechanism of depolymerization, very similar to those of various polystyrenes, can be proposed.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pola.1989.080270806

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