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Digitale Medien

Preparation and radical ring-opening polymerization of 2-substituted-4-methylene-1,3-dioxolanes (1989)

Hiraguri, Yoichi ; Endo, Takeshi

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 4403-4411

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Details

ISSN: 0887-624X

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: 2-Methyl-2-phenyl-4-methylene-1,3-dioxolane (IIa), 2-ethyl-2-phenyl-4-methylene-1,3-dioxolane (IIb), 2-phenyl-2-(n-propyl)-4-methylene-1,3-dioxolane (IIc), 2-phenyl-2-(i-propyl)-4-methylene-1,3-dioxolane (IId), 2-(n-heptyl)-2-phenyl-4-methylene-1,3-dioxolane (IIe), 2-methyl-2-(2-naphthyl)-4-methylene-1,3-dioxolane (IIf), and 2,2-diphenyl-4-methylene-1,3-dioxolane (IIg) were prepared and polymerized in the presence of a radical initiator. IIa-IIf were found to undergo vinyl polymerization with ring-opening reaction accompanying the elimination of ketone groups in bulk. IIg was found to undergo the quantitative ring-opening reaction accompanying the elimination of benzophenone in solution to obtain polyketone without any side reaction.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pola.1989.080271317

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